Logo CrioPura

A green solution
for water purification

Mission

Criopura - Mission
Water has been taken for granted for too long until the increasing pollution delineated the need to protect our provisions. Industrial consumption of water is a major drain on the world’s limited resources.

Every industry, needs thousands of tons of fresh water every day, all around the world, producing wastewater with different contaminants.

Then how can we protect our natural capital? Wastewater treatment, conducted by using absorbing materials, is an effective solution. Removing contaminants affords clean water, suitable for safely returning to the environment. In this context, we are proud to present CrioPurA, an innovative technology for industrial wastewater and groundwater remediation

Fundings

Awards

Technology

Macroporous polymeric cryogel based on N-alkyl-D-glucamine to sequester and/or remove toxic contaminants.
N-methyl-D-glucamine (NMG) is a chelating species used for environmental applications thanks to its high chelating efficiency towards metal anions.
The technology presented, called CrioPurA, is a realization of NMG-based hydrogels, produced by cryo-polymerization in water. The synthesis of polymeric materials, functionalized ad hoc with chelating groups, allows low costs and eco-sustainable materials to subsequently obtain adsorbent materials. In particular, the technique adopted for the realization of the material allows to obtain structures and shapes of different sizes, with high porosity, permeability and excellent sequestering action towards boron, arsenic, chromium and other metals.

CrioPura can be regenerated, reused and used selectively for water treatment. The technology finds application as an exchange resin for the removal of inorganic pollutants from water. This allows to find a valid application and integration in the cycle of tertiary wastewater treatments, without additional costs for the implementation of the plant, as a filter for industrial plants (tanning, dyes, textiles, microelectronics), groundwater, in agriculture for boron removal.

In some areas where the presence of As (V) in water for domestic use is significantly higher than the legal limits imposed by the WHO (10 μg/L), the CrioPurA application, considering the exceptional sequestering properties, could be more effective and with lower operating costs than current technologies.
Criopura - Spugna tecnology

Polymeric network resulting from a cryo-polymerization process, which, after a defrosting and drying step, assumes a macroporous structure that increases the operating flux

Polymer material that makes up the sponge composed of the almost exclusive chelating material significantly increasing the sequestration capacity of the filter

A natural material - loofah - is added to the filtering system during the polymerization process as an environmentally sustainable support for increasing mechanical capacity

Patents

Italian Patent No. 1020190000012339
• Granted
European Patent Application No. 20737048.7
• Under examination – View here
China Patent Application No. 202080052559.2
• Granted on 28/05/2024 CN114302771B
US Patent Application No. 17/626,227
• Examination not yet started – View here

Italy Patent Application No. 102023000009954 of 05/17/2023
• Extended until 05/17/2024

Criopura Filtri

Low operating costs

✓ Competitive advantage
Low energy consumption, due to lower pressure thanks to macroporous structure of the solution, and low maintenance costs, thanks to higher purification cycle capacity and reduced regeneration cycles required.

Operating pressure 0.1 bar -
two orders lower than the competitors

High pH range covered

✓ Competitive advantage
Higher sequestration capacity ranging from pH 2 to pH 9, making the solution reliable for different water scenarios

Wide pH range leads money and time-saving

High environmental sustainability

✓ Competitive advantage
Use of greener raw materials and chemicals for filter regeneration (over 40% of biodegradable compounds); moreover the production process occurs at 40°C using water as renewable solvent

LCA Study

How Criopura works

Criopura lab scale

Listen to the podcast about the research that led to CrioPurA created by Ilenia Di Martino
Click here to listen

Market

Market outlook

Water and Wastewater treatment is the process of treating water and making it useable for various purposes, such as drinking, irrigation, and industrial applications, removing undesired contaminants and impurities and minimizing the adverse effects for human health and the environment

Market overview

Global water and wastewater treatment market: 301.77 $ billion in 2022, with a CAGR of 7.5% between 2022 and 2030

Tertiary water and wastewater treatment market: 27,931 $ mln in 2022, with a CAGR of 4.8% between 2023 and 2030

Drivers

Restrains

Regulations

*Note: Note: In October 2023, the European Council reached an agreement on a proposal to revise the Directive 1991/271/EEC, which regulates urban waste-water treatment (link).
Sources: Water and Wastewater Treatment Equipment, Market Analysis, 2023 ; Sustainable technologies for water purification from heavy metals: review and analysis, Bolisetty et al., 2019 ; Fortune business insights ; Precedence research ; Water and Wastewater Treatment Equipment, Market Analysis, Grand View Research, 2023 ; Global Water and Wastewater Treatment Equipment Market 2023-2027, Technavio, 2023 ; Global Commercial Water Treatment Equipment Market 2023-2027, Technavio, 2023.

Team

CrioPurA was born from a group of cnr researchers united to address growing environmental concerns.

Following a continuous commitment to counter this global challenge, ranging from the sustainable design of innovative materials for water remediation to the identification of microplastics in seawater and soil, the research group decided to leave their comfort zone. The invention of criopura could have led to yet another scientific article.

Still, instead, it was patented, taken out of the laboratory, and presented to groups of investors who believed in the technology.

Founders

Andrea Scamporrino

Researcher | Institute for Polymers, Composites and Biomaterials (IPCB), CNR | PhD in Polymeric Materials for Special Uses, Università degli Studi di Catania

Sabrina Carroccio

Researcher | Institute for Polymers, Composites and Biomaterials (IPCB), CNR | PhD in Chemistry, Università degli Studi di Catania

Francesca Cunsolo

Researcher | Institute of Biomolecular Chemistry (ICB), CNR | MSc in Organic Chemistry, Università di Catania and Senior Grant, Yale University

Tommaso Mecca

Researcher | Institute of Biomolecular Chemistry (ICB), CNR | PhD in Chemistry, Università degli Studi della Basilicata

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