A green solution
for water purification
Mission
Every industry, needs thousands of tons of fresh water every day, all around the world, producing wastewater with different contaminants.
Then how can we protect our natural capital? Wastewater treatment, conducted by using absorbing materials, is an effective solution. Removing contaminants affords clean water, suitable for safely returning to the environment. In this context, we are proud to present CrioPurA, an innovative technology for industrial wastewater and groundwater remediation
Fundings
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2020 - Programma Amico CNR
Funded by PoC MISE 80.000 € - TRL increase (1-->4) -
2022 - Eureka! Venture
230.000 € - Consolidation of technological maturity and technology scale-up (TRL 4 --> 7) -
2024 - Terranext
Cariplo Factory – in progress
Awards
- 2021 - Finalists EIT Jumpstarter - Manufacturing
- 2021 - Finalists StartCup CT 2021
Technology
N-methyl-D-glucamine (NMG) is a chelating species used for environmental applications thanks to its high chelating efficiency towards metal anions.
The technology presented, called CrioPurA, is a realization of NMG-based hydrogels, produced by cryo-polymerization in water. The synthesis of polymeric materials, functionalized ad hoc with chelating groups, allows low costs and eco-sustainable materials to subsequently obtain adsorbent materials. In particular, the technique adopted for the realization of the material allows to obtain structures and shapes of different sizes, with high porosity, permeability and excellent sequestering action towards boron, arsenic, chromium and other metals.
CrioPura can be regenerated, reused and used selectively for water treatment. The technology finds application as an exchange resin for the removal of inorganic pollutants from water. This allows to find a valid application and integration in the cycle of tertiary wastewater treatments, without additional costs for the implementation of the plant, as a filter for industrial plants (tanning, dyes, textiles, microelectronics), groundwater, in agriculture for boron removal.
In some areas where the presence of As (V) in water for domestic use is significantly higher than the legal limits imposed by the WHO (10 μg/L), the CrioPurA application, considering the exceptional sequestering properties, could be more effective and with lower operating costs than current technologies.
Polymeric network resulting from a cryo-polymerization process, which, after a defrosting and drying step, assumes a macroporous structure that increases the operating flux
Polymer material that makes up the sponge composed of the almost exclusive chelating material significantly increasing the sequestration capacity of the filter
A natural material - loofah - is added to the filtering system during the polymerization process as an environmentally sustainable support for increasing mechanical capacity
Patents
• Granted
• Under examination – View here
• Granted on 28/05/2024 CN114302771B
• Examination not yet started – View here
Italy Patent Application No. 102023000009954 of 05/17/2023
• Extended until 05/17/2024
Low operating costs
✓ Competitive advantage
Low energy consumption, due to lower pressure thanks to macroporous structure of the solution, and low maintenance costs, thanks to higher purification cycle capacity and reduced regeneration cycles required.
Operating pressure 0.1 bar
-
two orders lower than
the competitors
High pH range covered
✓ Competitive advantage
Higher sequestration capacity ranging from pH 2 to pH 9, making the solution reliable for different water scenarios
Wide pH range leads money and time-saving
High environmental sustainability
✓ Competitive advantage
Use of greener raw materials and chemicals for filter regeneration (over 40% of biodegradable compounds); moreover the production process occurs at 40°C using water as renewable solvent
LCA Study
How Criopura works
Criopura lab scale
Listen to the podcast about the research that led to CrioPurA created by Ilenia Di Martino
Click here to listen
Market
Market outlook
Market overview
Tertiary water and wastewater treatment market: 27,931 $ mln in 2022, with a CAGR of 4.8% between 2023 and 2030
Drivers
- Increasing global concerns regarding water scarcity
- Increasing demand for clean and industrial water
- Growing concern about the disposal of wastewater in water bodies
Restrains
- High operating costs related to the maintenance, operation, and monitoring of the treatment plant
- Operational and technical challenges for the installation and operation of equipment
Regulations
- Increasingly stringent regulations worldwide on the disposal limits of wastewater emissions*
Sources: Water and Wastewater Treatment Equipment, Market Analysis, 2023 ; Sustainable technologies for water purification from heavy metals: review and analysis, Bolisetty et al., 2019 ; Fortune business insights ; Precedence research ; Water and Wastewater Treatment Equipment, Market Analysis, Grand View Research, 2023 ; Global Water and Wastewater Treatment Equipment Market 2023-2027, Technavio, 2023 ; Global Commercial Water Treatment Equipment Market 2023-2027, Technavio, 2023.
Team
Following a continuous commitment to counter this global challenge, ranging from the sustainable design of innovative materials for water remediation to the identification of microplastics in seawater and soil, the research group decided to leave their comfort zone. The invention of criopura could have led to yet another scientific article.
Still, instead, it was patented, taken out of the laboratory, and presented to groups of investors who believed in the technology.
Founders
Andrea Scamporrino
Researcher | Institute for Polymers, Composites and Biomaterials (IPCB), CNR | PhD in Polymeric Materials for Special Uses, Università degli Studi di Catania
Sabrina Carroccio
Researcher | Institute for Polymers, Composites and Biomaterials (IPCB), CNR | PhD in Chemistry, Università degli Studi di Catania
Francesca Cunsolo
Researcher | Institute of Biomolecular Chemistry (ICB), CNR | MSc in Organic Chemistry, Università di Catania and Senior Grant, Yale University
Tommaso Mecca
Researcher | Institute of Biomolecular Chemistry (ICB), CNR | PhD in Chemistry, Università degli Studi della Basilicata
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